Ferrocene-derived P,N ligands: Synthesis and application in enantioselective catalysis
نویسندگان
چکیده
Due to their unique steric and electronic properties, air-stability and modular structure, chiral hybrid P,N-ferrocenyl ligands play a prominent role in the field of asymmetric catalysis. This report aims to give a concise introduction to the syntheses of chiral hybrid P,N-ferrocenyl ligands and presents an overview of their application in enantioselective catalysis. This review is of special interest for chemists working on ligand design and asymmetric catalysis, as well as for the broader organic and inorganic community. * Corresponding author. Tel.: +31-40-247-3623; e-mail: [email protected] * Corresponding author. Tel.: +32-9-264-44-80; fax: +32-9-264-49-98; e-mail: [email protected]
منابع مشابه
An efficient and highly stereoselective synthesis of new P-chiral 1,5-diphosphanylferrocene ligands and their use in enantioselective hydrogenation.
An efficient and highly stereoselective synthesis of P-chiral 1,5-diphosphanylferrocene ligands has been developed, and the introduction of P-chirality in ferrocene-based phosphine ligands enhances the enantioselective discrimination produced by the corresponding catalyst when matching of the planar chirality, the chirality at carbon and the chirality at phosphorus occurs.
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